Batman Season 2 - Episode 39 (CERTIFIED)

Batman manages to break free from his chains and uses his strength to pry open the giant clam, saving Robin just in time.

The Joker breaks the Penguin out of Gotham State Prison to help him complete his "Zodiac" themed crime spree. Their primary goal is to collect a $10 million ransom by threatening to turn Gotham City's water supply into jelly. Batman Season 2 - Episode 39

(in one of his earliest TV appearances) plays a delivery boy for the Penguin. Key Trivia Batman manages to break free from his chains